Asymmetric spin crossover behaviour and evidence of light-induced excited spin state trapping in a dinuclear iron(II) helicate
Language
en
Article de revue
This item was published in
Chemical Communications. 2009 n° 2, p. 221-223
Royal Society of Chemistry
English Abstract
Reported herein are the synthesis, structural and magnetic characterisation of a dinuclear FeII triple helicate that displays an unprecedented reversible asymmetric high spin to low spin crossover characterised by a thermal ...Read more >
Reported herein are the synthesis, structural and magnetic characterisation of a dinuclear FeII triple helicate that displays an unprecedented reversible asymmetric high spin to low spin crossover characterised by a thermal hysteresis: indeed the high spin state can be recovered by white light irradiation at 10 K.Read less <
Italian Keywords
Iron(II)
Spin crossover
LIESST
Origin
Hal imported