Ultrafast and continuous synthesis of crystalline ferrite nanoparticles in supercritical ethanol
Language
en
Article de revue
This item was published in
Nanoscale. 2013, vol. 5, n° 5, p. 2126-2132
Royal Society of Chemistry
English Abstract
Magnetic nanoparticles (NPs) are of increasing interest in various industrially relevant products. For these, the development of greener and faster approaches facilitating scaling-up production is of paramount importance. ...Read more >
Magnetic nanoparticles (NPs) are of increasing interest in various industrially relevant products. For these, the development of greener and faster approaches facilitating scaling-up production is of paramount importance. Here, we report a novel, green and potentially scalable approach for the continuous and ultrafast (90 s) synthesis of superparamagnetic ferrite NPs (MnFe(2)O(4), Fe(3)O(4)) in supercritical ethanol (scEtOH) at a fairly moderate temperature (260 °C). ScEtOH exhibits numerous advantages such as its production from bio-resources, its lack of toxicity and its relatively low supercritical coordinates (p(c) = 6.39 MPa and T(c) = 243 °C), being therefore appropriate for the development of sustainable technologies. The present study is completed by the investigation of both in situ and ex situ NP surface functionalization. The as-obtained nanoparticles present good crystallinity, sizes below 8 nm, superparamagnetic behavior at room temperature and high saturation magnetization. Moreover, depending on the capping strategy, the ferrite NPs present extended (for in situ coated NPs) or short-term (for ex situ coated NPs) colloidal stability.Read less <
English Keywords
Supercritical fluids
Ethanol
Nanoparticles
Ferrites
Origin
Hal imported