Hydrostatic pressure investigation of the spin crossover compound [Fe(PM―BiA)<sub>2</sub>(NCS)<sub>2</sub>] polymorph I using reflectance detection
ROTARU, Aurelian
Groupe d'Etude de la Matière Condensée [GEMAC]
Department of Solid State and Theoretical Physics
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Groupe d'Etude de la Matière Condensée [GEMAC]
Department of Solid State and Theoretical Physics
ROTARU, Aurelian
Groupe d'Etude de la Matière Condensée [GEMAC]
Department of Solid State and Theoretical Physics
< Reduce
Groupe d'Etude de la Matière Condensée [GEMAC]
Department of Solid State and Theoretical Physics
Language
en
Article de revue
This item was published in
Journal of Applied Physics. 2009, vol. 106, n° 5, p. 053515
American Institute of Physics
English Abstract
We investigated by diffuse reflectivity the effect of hydrostatic pressure (1–1800 bar) on the thermal spin transition of Fe(PM−BiA)2(NCS)2 polymorph I, where PM=N-2-pyridylmethylene and BiA=4-aminobiphenyl. We evidenced ...Read more >
We investigated by diffuse reflectivity the effect of hydrostatic pressure (1–1800 bar) on the thermal spin transition of Fe(PM−BiA)2(NCS)2 polymorph I, where PM=N-2-pyridylmethylene and BiA=4-aminobiphenyl. We evidenced the onset of a progressive transformation into a phase of higher cooperativity which cannot be assigned to polymorph II. This result is discussed with respect to previous pressure investigations.Read less <
Origin
Hal imported