Reversible Thermally and Photoinduced Electron Transfer in a Cyano-Bridged {Fe2Co2} Square Complex
LI, Dongfeng
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
Centre de recherches Paul Pascal [CRPP]
See more >
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
Centre de recherches Paul Pascal [CRPP]
LI, Dongfeng
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
Centre de recherches Paul Pascal [CRPP]
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
Centre de recherches Paul Pascal [CRPP]
MATHONIÈRE, Corine
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
< Reduce
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Language
en
Article de revue
This item was published in
Angewandte Chemie International Edition. 2010, vol. 49, n° 22, p. pp. 3752-3756
Wiley-VCH Verlag
English Abstract
Flip to be square: Structural, spectroscopic, magnetic, and photomagnetic studies conclusively demonstrate that a tetranuclear cyanometalate {Fe2Co2} complex undergoes reversible thermally and light-induced changes in ...Read more >
Flip to be square: Structural, spectroscopic, magnetic, and photomagnetic studies conclusively demonstrate that a tetranuclear cyanometalate {Fe2Co2} complex undergoes reversible thermally and light-induced changes in optical and magnetic properties. This instability is induced by an intramolecular electron transfer, as oberved in three-dimensional Co/Fe Prussian blue compounds (see picture).Read less <
English Keywords
bistability
cyanometatlates
electron transfer
magnetic properties
photochromism
thermochromism
Origin
Hal imported