Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp)(2) (NCS)(2) ]⋅py.
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
| dc.contributor.author | SHEPHERD, Helena | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | PALAMARCIUC, Tatiana | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | ROSA, Patrick | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GUIONNEAU, Philippe | |
| hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
| dc.contributor.author | MOLNÁR, Gábor | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-François | |
| hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
| dc.contributor.author | BOUSSEKSOU, Azzedine | |
| dc.date.issued | 2012 | |
| dc.identifier.issn | 1433-7851 | |
| dc.description.abstractEn | A scissor-like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp)(2) (NCS)(2) ]⋅py (see picture; dpp=dipyrido[3,2-a:2'3'-c]phenazine), C gray, N blue, S yellow, Fe red). The same mechanism is also responsible for suppressing the high-spin to low-spin transition under pressure. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | Iron | |
| dc.subject.en | Mechanical properties | |
| dc.subject.en | Molecular materials | |
| dc.subject.en | N ligands | |
| dc.subject.en | Spin crossover | |
| dc.title.en | Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp)(2) (NCS)(2) ]⋅py. | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/anie.201108919 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Angewandte Chemie International Edition | |
| bordeaux.page | 3910-3914 | |
| bordeaux.volume | 51 | |
| bordeaux.issue | 16 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00694977 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00694977v1 | |
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