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Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp)(2) (NCS)(2) ]⋅py.

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorSHEPHERD, Helena
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPALAMARCIUC, Tatiana
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROSA, Patrick
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorMOLNÁR, Gábor
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorBOUSSEKSOU, Azzedine
dc.date.issued2012
dc.identifier.issn1433-7851
dc.description.abstractEnA scissor-like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp)(2) (NCS)(2) ]⋅py (see picture; dpp=dipyrido[3,2-a:2'3'-c]phenazine), C gray, N blue, S yellow, Fe red). The same mechanism is also responsible for suppressing the high-spin to low-spin transition under pressure.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enIron
dc.subject.enMechanical properties
dc.subject.enMolecular materials
dc.subject.enN ligands
dc.subject.enSpin crossover
dc.title.enAntagonism between extreme negative linear compression and spin crossover in [Fe(dpp)(2) (NCS)(2) ]⋅py.
dc.typeArticle de revue
dc.identifier.doi10.1002/anie.201108919
dc.subject.halChimie/Matériaux
bordeaux.journalAngewandte Chemie International Edition
bordeaux.page3910-3914
bordeaux.volume51
bordeaux.issue16
bordeaux.peerReviewedoui
hal.identifierhal-00694977
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00694977v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.date=2012&rft.volume=51&rft.issue=16&rft.spage=3910-3914&rft.epage=3910-3914&rft.eissn=1433-7851&rft.issn=1433-7851&rft.au=SHEPHERD,%20Helena&PALAMARCIUC,%20Tatiana&ROSA,%20Patrick&GUIONNEAU,%20Philippe&MOLN%C3%81R,%20G%C3%A1bor&rft.genre=article


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