Self-assembly of [CuIITbIII]3+ and [W(CN)8]3− tectons: a case study of a mixture containing two complexes showing slow-relaxation of the magnetization
JEON, Ie-Rang
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
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Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
JEON, Ie-Rang
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
< Reduce
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Language
en
Article de revue
This item was published in
Dalton Transactions. 2012, vol. 41, p. pp. 13578-13581
Royal Society of Chemistry
English Abstract
The reaction of [Cu(valen)] with Tb(NO3)3 and (Bu3NH)3- [W(CN)8] affords two types of crystals: [{W(CN)8}Cu(valen)- Tb(OH2)5]*2H2O (1, a discrete trinuclear complex) and [{W(CN)8}Cu(valen)Tb(OH2)4]*CH3CN*H2O (2, an infinite ...Read more >
The reaction of [Cu(valen)] with Tb(NO3)3 and (Bu3NH)3- [W(CN)8] affords two types of crystals: [{W(CN)8}Cu(valen)- Tb(OH2)5]*2H2O (1, a discrete trinuclear complex) and [{W(CN)8}Cu(valen)Tb(OH2)4]*CH3CN*H2O (2, an infinite zig-zag chain), both compounds showing slow relaxation of the magnetization (H2valen is the Schiff base resulting from the reaction of o-vanillin with 1,2-ethanediamine).Read less <
Keywords
Magnetism
Single-chain magnets
Origin
Hal imported