STURM, Ludmilla; ARIBOT, Frederic; SOLIMAN, Luc; BOCK, Harald; DUROLA, Fabien

doi:10.1002/ejoc.202200196

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STURM, Ludmilla

Centre de Recherche Paul Pascal [CRPP]

ARIBOT, Frederic

Centre de Recherche Paul Pascal [CRPP]

SOLIMAN, Luc
Centre de Recherche Paul Pascal [CRPP]

Idioma

Article de revue

Este ítem está publicado en

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2022

Resumen en inglés

An efficient and versatile synthetic approach has been developed for the synthesis of large carboxy-substituted polycyclic arenes. This strategy relies on Perkin reactions between arylacetic and arylglyoxylic acids for the formation of flexible precursors. A subsequent rigidification step, by catalyst- or light-induced intramolecular cyclization reactions, then yields fully condensed polycyclic aromatic compounds. Protection and deprotection techniques have been developed to allow the controlled assembly of a large number of building blocks. This method can now be applied to the formation of planar or non-planar, linear or macrocyclic species of various sizes.< Leer menos

Palabras clave en inglés

Helicenes

Macrocycles

Perkin reaction

Polycyclic aromatic compounds

Synthetic methods

URI

https://oskar-bordeaux.fr/handle/20.500.12278/140173

DOI

http://dx.doi.org/10.1002/ejoc.202200196

Proyecto ANR

Nanobagues aromatiques - ANR-13-JS07-0009
Nano-rubans cycliques aromatiques - ANR-20-CE07-0014

Centros de investigación

Centre de Recherche Paul Pascal (CRPP) - UMR 5031