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Resetting chemical clocks of hot cores based on S-bearing molecules

hal.structure.identifierUniversité Sciences et Technologies - Bordeaux 1 [UB]
hal.structure.identifierLaboratoire d'astrodynamique, d'astrophysique et d'aéronomie de bordeaux [L3AB]
hal.structure.identifierObservatoire aquitain des sciences de l'univers [OASU]
hal.structure.identifierLaboratoire d'Astrophysique de Bordeaux [Pessac] [LAB]
dc.contributor.authorWAKELAM, Valentine
hal.structure.identifierINAF - Osservatorio Astrofisico di Arcetri [OAA]
dc.contributor.authorCASELLI, Paola
hal.structure.identifierLaboratoire d'Astrophysique de Grenoble [LAOG]
dc.contributor.authorCECCARELLI, Cecilia
hal.structure.identifierThe Ohio State University [Columbus] [OSU]
dc.contributor.authorHERBST, Eric
hal.structure.identifierLaboratoire d'astrodynamique, d'astrophysique et d'aéronomie de bordeaux [L3AB]
hal.structure.identifierObservatoire aquitain des sciences de l'univers [OASU]
hal.structure.identifierLaboratoire d'Astrophysique de Bordeaux [Pessac] [LAB]
hal.structure.identifierUniversité Sciences et Technologies - Bordeaux 1 [UB]
dc.contributor.authorCASTETS, Alain
dc.date.issued2004
dc.identifier.issn0004-6361
dc.description.abstractEnWe report a theoretical study of sulphur chemistry, as applied to hot cores, where S-bearing molecular ratios have been previously proposed and used as chemical clocks. As in previous models, we follow the S-bearing molecular composition after the injection of grain mantle components into the gas phase. For this study, we developed a time-dependent chemical model with up-to-date reaction rate coefficients. We ran several cases, using different realistic chemical compositions for the grain mantles and for the gas prior to mantle evaporation. The modeling shows that S-bearing molecular ratios depend very critically on the gas temperature and density, the abundance of atomic oxygen, and, most importantly, on the form of sulphur injected in the gas phase, which is very poorly known. Consequently, ratios of S-bearing molecules cannot be easily used as chemical clocks. However, detailed observations and careful modeling of both physical and chemical structure can give hints on the source age and constrain the mantle composition (i.e. the form of sulphur in cold molecular clouds) and, thus, help to solve the mystery of the sulphur depletion. We analyse in detail the cases of Orion and IRAS16293-2422. The comparison of the available observations with our model suggests that the majority of sulphur released from the mantles is mainly in, or soon converted into, atomic form.
dc.language.isoen
dc.publisherEDP Sciences
dc.subjectabundances
dc.subjectmolecules
dc.subjectstar formation
dc.title.enResetting chemical clocks of hot cores based on S-bearing molecules
dc.typeArticle de revue
dc.identifier.doi10.1051/0004-6361:20047186
dc.subject.halPhysique [physics]/Astrophysique [astro-ph]/Cosmologie et astrophysique extra-galactique [astro-ph.CO]
dc.subject.halPlanète et Univers [physics]/Astrophysique [astro-ph]
dc.identifier.arxivastro-ph/0404246
bordeaux.journalAstronomy and Astrophysics - A&A
bordeaux.page159
bordeaux.volume422
bordeaux.peerReviewedoui
hal.identifierhal-00001445
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00001445v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Astronomy%20and%20Astrophysics%20-%20A&A&rft.date=2004&rft.volume=422&rft.spage=159&rft.epage=159&rft.eissn=0004-6361&rft.issn=0004-6361&rft.au=WAKELAM,%20Valentine&CASELLI,%20Paola&CECCARELLI,%20Cecilia&HERBST,%20Eric&CASTETS,%20Alain&rft.genre=article


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