Resetting chemical clocks of hot cores based on S-bearing molecules
WAKELAM, Valentine
Université Sciences et Technologies - Bordeaux 1 [UB]
Laboratoire d'astrodynamique, d'astrophysique et d'aéronomie de bordeaux [L3AB]
Observatoire aquitain des sciences de l'univers [OASU]
Laboratoire d'Astrophysique de Bordeaux [Pessac] [LAB]
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Université Sciences et Technologies - Bordeaux 1 [UB]
Laboratoire d'astrodynamique, d'astrophysique et d'aéronomie de bordeaux [L3AB]
Observatoire aquitain des sciences de l'univers [OASU]
Laboratoire d'Astrophysique de Bordeaux [Pessac] [LAB]
WAKELAM, Valentine
Université Sciences et Technologies - Bordeaux 1 [UB]
Laboratoire d'astrodynamique, d'astrophysique et d'aéronomie de bordeaux [L3AB]
Observatoire aquitain des sciences de l'univers [OASU]
Laboratoire d'Astrophysique de Bordeaux [Pessac] [LAB]
Université Sciences et Technologies - Bordeaux 1 [UB]
Laboratoire d'astrodynamique, d'astrophysique et d'aéronomie de bordeaux [L3AB]
Observatoire aquitain des sciences de l'univers [OASU]
Laboratoire d'Astrophysique de Bordeaux [Pessac] [LAB]
CASTETS, Alain
Laboratoire d'astrodynamique, d'astrophysique et d'aéronomie de bordeaux [L3AB]
Observatoire aquitain des sciences de l'univers [OASU]
Laboratoire d'Astrophysique de Bordeaux [Pessac] [LAB]
Université Sciences et Technologies - Bordeaux 1 [UB]
< Reduce
Laboratoire d'astrodynamique, d'astrophysique et d'aéronomie de bordeaux [L3AB]
Observatoire aquitain des sciences de l'univers [OASU]
Laboratoire d'Astrophysique de Bordeaux [Pessac] [LAB]
Université Sciences et Technologies - Bordeaux 1 [UB]
Language
en
Article de revue
This item was published in
Astronomy and Astrophysics - A&A. 2004, vol. 422, p. 159
EDP Sciences
English Abstract
We report a theoretical study of sulphur chemistry, as applied to hot cores, where S-bearing molecular ratios have been previously proposed and used as chemical clocks. As in previous models, we follow the S-bearing molecular ...Read more >
We report a theoretical study of sulphur chemistry, as applied to hot cores, where S-bearing molecular ratios have been previously proposed and used as chemical clocks. As in previous models, we follow the S-bearing molecular composition after the injection of grain mantle components into the gas phase. For this study, we developed a time-dependent chemical model with up-to-date reaction rate coefficients. We ran several cases, using different realistic chemical compositions for the grain mantles and for the gas prior to mantle evaporation. The modeling shows that S-bearing molecular ratios depend very critically on the gas temperature and density, the abundance of atomic oxygen, and, most importantly, on the form of sulphur injected in the gas phase, which is very poorly known. Consequently, ratios of S-bearing molecules cannot be easily used as chemical clocks. However, detailed observations and careful modeling of both physical and chemical structure can give hints on the source age and constrain the mantle composition (i.e. the form of sulphur in cold molecular clouds) and, thus, help to solve the mystery of the sulphur depletion. We analyse in detail the cases of Orion and IRAS16293-2422. The comparison of the available observations with our model suggests that the majority of sulphur released from the mantles is mainly in, or soon converted into, atomic form.Read less <
Keywords
abundances
molecules
star formation
Origin
Hal imported