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hal.structure.identifierAMOR 2012
dc.contributor.authorDRUARD, C.
hal.structure.identifierAMOR 2012
dc.contributor.authorWAKELAM, Valentine
dc.date.created2012-07-23
dc.date.issued2012
dc.identifier.issn0035-8711
dc.description.abstractEnThe form of depleted sulphur in dense clouds is still unknown. Until now, only two molecules, OCS and SO2, have been detected in interstellar ices but cannot account for the elemental abundance of sulphur observed in diffuse medium. Chemical models suggest that solid H2S is the main form of sulphur in denser sources but observational constraints exist that infirm this hypothesis. We have used the Nautilus gas-grain code in which new chemical reactions have been added, based on recent experiments of H2S ice irradiation with UV photons and high energy protons. In particular, we included the new species Sn, H2Sn and C2S. We found that at the low temperature observed in dense clouds, i.e. 10 K, these new molecules are not efficiently produced and our modifications of the network do not change the previous pre- dictions. At slightly higher temperature, 20 K in less dense clouds or in the proximity of protostars, H2S abundance on the surfaces is strongly decreased in favor of the polysulfanes H2S3. Such a result can also be obtained if the diffusion barriers on the grains are less im- portant. In the context of the life cycle of interstellar clouds and the mixing between diffuse and denser parts of the clouds, the depletion of sulphur in the form of polysulfanes or other sulphur polymers, may have occurred in regions where the temperature is slightly higher than the cold inner parts of the clouds.
dc.language.isoen
dc.publisherOxford University Press (OUP): Policy P - Oxford Open Option A
dc.subject.enAstrophysics
dc.subject.enGalaxy Astrophysics
dc.title.enPolysulfanes on interstellar grains as a possible reservoir of interstellar sulphur
dc.typeArticle de revue
dc.identifier.doi10.1111/j.1365-2966.2012.21712.x
dc.subject.halPlanète et Univers [physics]/Astrophysique [astro-ph]/Cosmologie et astrophysique extra-galactique [astro-ph.CO]
dc.subject.halPhysique [physics]/Astrophysique [astro-ph]/Cosmologie et astrophysique extra-galactique [astro-ph.CO]
dc.identifier.arxiv1207.5325
bordeaux.journalMonthly Notices of the Royal Astronomical Society
bordeaux.page354-359
bordeaux.volume426
bordeaux.issue1
bordeaux.peerReviewedoui
hal.identifierhal-00733718
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00733718v1
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