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dc.rights.licenseopenen_US
dc.relation.isnodouble54f40d82-c1ee-4a51-a7dc-a3873ce4928d*
dc.relation.isnodoubled3e9affd-c524-4b95-a31c-566d7ca6ec51*
dc.contributor.authorGAUTHIER, Maxime
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorKOEHLER, Victor
dc.contributor.authorCLAVEL, Caroline
hal.structure.identifierInstitut Européen de Chimie et Biologie [IECB]
dc.contributor.authorKAUFFMANN, Brice
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorHUC, Ivan
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorFERRAND, Yann
dc.contributor.authorCOUTROT, Frederic
dc.date.accessioned2021-07-05T09:32:01Z
dc.date.available2021-07-05T09:32:01Z
dc.date.issued2021
dc.identifier.issn1433-7851en_US
dc.identifier.otherhttps://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202100349&file=anie202100349-sup-0001-misc_information.pdfen_US
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/94970
dc.description.abstractEnThe design and synthesis of a novel rotaxane/foldaxane hybrid architecture is reported. The winding of an aromatic oligoamide helix host around a dumbbell-shaped thread-like guest, or axle, already surrounded by a macrocycle was evidenced by NMR spectroscopy and X-ray crystallography. The process proved to depend on the position of the macrocycle along the axle and the associated steric hindrance. The macrocycle thus behaves as a switchable shield that modulates the affinity of the helix for the axle. Reciprocally, the foldamer helix acts as a supramolecular auxiliary that compartmentalizes the axle. In some cases, the macrocycle is forced to move along the axle to allow the foldamer to reach its best recognition site.
dc.description.sponsorshipDes FoldaRotaxanes pour la Synthèse généralisée de Molécules Entrelacées Improbables - ANR-17-CE07-0014en_US
dc.language.isoENen_US
dc.subject.encrystallography
dc.subject.enfoldamers
dc.subject.enmolecular motion
dc.subject.enrotaxanes
dc.title.enInterplay between a Foldamer Helix and a Macrocycle in a Foldarotaxane Architecture
dc.typeArticle de revueen_US
dc.identifier.doi10.1002/anie.202100349en_US
dc.subject.halChimie/Matériauxen_US
bordeaux.journalAngewandte Chemie-International Editionen_US
bordeaux.page8380-8384en_US
bordeaux.volume60en_US
bordeaux.hal.laboratoriesInstitut de Chimie & de Biologie des Membranes & des Nano-objets (CBMN) - UMR 5248en_US
bordeaux.issue15en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionBordeaux INPen_US
bordeaux.institutionCNRSen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
hal.identifierhal-03247517
hal.exportfalse
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