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dc.rights.licenseopenen_US
hal.structure.identifierUnité de Recherche Oenologie [Villenave d'Ornon] [OENO]
dc.contributor.authorSHINKARUK, Svitlana
hal.structure.identifierUnité de Recherche Oenologie [Villenave d'Ornon] [OENO]
dc.contributor.authorFLOCH, Morgan
dc.contributor.authorPRIDA, Andréi
hal.structure.identifierUnité de Recherche Oenologie [Villenave d'Ornon] [OENO]
dc.contributor.authorDARRIET, Philippe
IDREF: 077788834
hal.structure.identifierUnité de Recherche Oenologie [Villenave d'Ornon] [OENO]
dc.contributor.authorPONS, Alexandre
dc.date.accessioned2020-06-29T14:07:08Z
dc.date.available2020-06-29T14:07:08Z
dc.date.issued2019
dc.identifier.issn0021-8561en_US
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/8305
dc.description.abstractEnVolatile extractive compounds from high-quality oak wood (Quercus sp.) are responsible for important pleasant olfactory notes, such as coconut, wood, vanilla, caramel, and spice. Recently, a new off-flavor reminiscent of rancid butter has been detected in oak wood. Using gas chromatography-olfactometry (GC-O) coupled to several detection modes, such as nitrogen-phosphorus detection (GC-O-NPD) or mass spectrometry (GC-O-MS) and multidimensional GC-O coupled to time-of-flight mass spectrometry, six compounds containing nitrogen atoms were identified. The volatiles were suggested to belong to 2,5-disubstituted pyrazines family, which was confirmed by comparison with synthetic reference compounds. For this purpose, symmetric and dissymmetric 2,5-dialkylpyrazines were prepared. from methyl esters of corresponding aliphatic amino acids (Val, Leu, and Ile) by a three-step, one-pot reaction under mild reducing conditions. Organoleptic descriptors and odor detection thresholds were also determined, whereas a bacterial origin explaining these off-flavors was hypothesized.
dc.language.isoENen_US
dc.subject.enAroma
dc.subject.enBarrel Aging
dc.subject.enDialkylpyrazine
dc.subject.enOak Wood
dc.subject.enOff-Flavor
dc.subject.enWine
dc.title.enIdentification of dialkylpyrazines off-flavors in oak wood
dc.title.alternativeJ. agric. food chem.en_US
dc.typeArticle de revueen_US
dc.identifier.doi10.1021/acs.jafc.9b03185en_US
dc.subject.halSciences du Vivant [q-bio]/Biologie végétaleen_US
dc.identifier.pubmed31423769en_US
bordeaux.journalJournal of Agricultural and Food Chemistryen_US
bordeaux.page10137-10144en_US
bordeaux.volume67en_US
bordeaux.hal.laboratoriesOenologie - EA 4577en_US
bordeaux.issue36en_US
bordeaux.institutionBordeaux INPen_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
hal.exportfalse
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