Di- and trivalent rare earth complexes stabilized by sterically demanding aminopyridinato ligands as initiators in ring-opening polymerization reactions of epsilon-caprolactone
Idioma
en
Article de revue
Este ítem está publicado en
Journal of Polymer Science Part A: Polymer Chemistry. 2007, vol. 45, n° 16, p. 3611-3619
Wiley
Resumen en inglés
Salt elimination protocols using Ap*K {Ap*H = (2,6-diisopropyl-phenyl)[6-(2,4,6-triisopropyl-phenyl)-pyridin-2-y1]-amine} lead to the rare earth aminopyridinato complex [Ap*LuCl2(thf)(2)], 4. Results of X-ray crystal ...Leer más >
Palabras clave en inglés
aminopyridinato complex [Ap*LuCl2(thf)(2)]
X-ray crystal structure analyses
rare earth
ring-opening polymerization of epsilon-caprolactone
synthesis
aminopyridinato ligands
borohydride
catalysts
polyesters