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hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorBABIN, Jerome
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorRODRIGUEZ-HERNANDEZ, Juan
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 3 LCPO : Polymer Self-Assembly & Life Sciences
dc.contributor.authorLECOMMANDOUX, Sebastien
dc.contributor.authorKLOK, H. A.
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorACHARD, Marie-France
dc.date.accessioned2020
dc.date.available2020
dc.date.created2005
dc.date.issued2005
dc.identifier.issn1359-6640
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20707
dc.description.abstractEnThe synthesis, solution and solid state self-assembly properties of a series of polyisoprene-b-poly(epsilon-benzyloxycarbonyl-L-lysine) PI-b-PZLys and polyisoprene-b-poly(L-lysine) PI-b-PLys block copolymers have been examined. The formation of stimuli-responsive micelles in water has been studied as a function of pH and ionic strength using static and dynamic light scattering, UV-circular dichroism and transmission electron microscopy. The observed change in the micelles dimensions has been directly attributed to the conformational transition in the secondary structure of polypeptide chains. In bulk, these rod-coil copolymers form self-assembled structures that have been characterized using DSC, DMA, WAXS and SAXS techniques. Hexagonal in lamellar (HL) and more interestingly hexagonal in hexagonal (HH) morphologies have been evidenced as a function of the chemical composition.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enSCATTERING
dc.subject.enEQUILIBRIUM
dc.subject.enPHASE-BEHAVIOR
dc.subject.enL-LYSINE
dc.subject.enMORPHOLOGY
dc.subject.enMICROPHASE SEPARATION
dc.subject.enSUPRAMOLECULAR MATERIALS
dc.subject.enDIBLOCK COPOLYMERS
dc.subject.enPOLYPEPTIDE BLOCK
dc.subject.enTRANSITION
dc.title.enSelf-assembled nanostructures from peptide-synthetic hybrid block copolymers: Complex, stimuli-responsive rod-coil architectures
dc.typeArticle de revue
dc.identifier.doi10.1039/b403203a
dc.subject.halChimie/Polymères
bordeaux.journalFaraday Discussions
bordeaux.page179-192
bordeaux.volume128
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00392723
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00392723v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Faraday%20Discussions&rft.date=2005&rft.volume=128&rft.spage=179-192&rft.epage=179-192&rft.eissn=1359-6640&rft.issn=1359-6640&rft.au=BABIN,%20Jerome&RODRIGUEZ-HERNANDEZ,%20Juan&LECOMMANDOUX,%20Sebastien&KLOK,%20H.%20A.&ACHARD,%20Marie-France&rft.genre=article


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