Retarded anionic polymerization (RAP) of styrene and dienes
CARLOTTI, Stéphane
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
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Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
CARLOTTI, Stéphane
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
DEFFIEUX, Alain
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
< Réduire
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Langue
en
Article de revue
Ce document a été publié dans
Polymer. 2009, vol. 50, n° 14, p. 3057-3067
Elsevier
Résumé en anglais
The possibilities to achieve a quantitative living-like anionic polymerization of styrene and dienes in the absence of solvent and at elevated temperature and using inexpensive initiating systems were explored to make the ...Lire la suite >
The possibilities to achieve a quantitative living-like anionic polymerization of styrene and dienes in the absence of solvent and at elevated temperature and using inexpensive initiating systems were explored to make the anionic polymerization competitive with industrial radical processes and allow the industrial production of anionic polystyrene (PS). It implied at first to control the reactivity and stability of initiating and propagating active species in such unusual operating conditions. To achieve these goals the so-called styrene and butadiene ''Retarded Anionic Polymerization'' (RAP) have been developed. This review focuses on the description of different bimetallic anionic polymerization systems which are able to approach or fulfill the industrial conditions for styrene and dienes anionic polymerizations.< Réduire
Mots clés en anglais
ate complex
butadiene
styrene
retarded anionic polymerization
Origine
Importé de halUnités de recherche