LE MEUR, Anne-Claire; AYMONIER, Cyril; HÉROGUEZ, Valérie

doi:10.1002/pola.25941

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LE MEUR, Anne-Claire
Bertin Technologies [Bertin Technologies]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering

AYMONIER, Cyril
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

HÉROGUEZ, Valérie
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering

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Journal of Polymer Science Part A: Polymer Chemistry. 2012, vol. 50, n° 9, p. 1746-1754

Wiley

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This article proposes the first report on the synthesis of nanometric crosslinked polynorbornene particles by ring-opening metathesis polymerization in dispersion using ruthenium-based complex (PCy3)2Cl2Ru=CHPh as initiator. Stable but raspberry-shaped particles were obtained. In this study, a particular attention was paid to the influence of the crosslinker nature and addition mode on reaction kinetics and morphology of the latex particles.< Leer menos

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Dispersion polymerization

Crosslinked particles

Poly norbornene

Ring-opening metathesis polymerization (ROMP)

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Crosslinked polynorbornene particles synthesis by ring-opening metathesis polymerization in dispersion

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