Design of Well-Defined Monofunctionalized Poly(3-hexylthiophene)s: Toward the Synthesis of Semiconducting Graft Copolymers
BROCHON, Cyril
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
CLOUTET, Eric
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
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Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
BROCHON, Cyril
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
CLOUTET, Eric
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
FLEURY, Guillaume
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
CRAMAIL, Henri
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
HADZIIOANNOU, Georges
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
< Réduire
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Langue
en
Article de revue
Ce document a été publié dans
Macromolecular Rapid Communications. 2012, vol. 33, n° 8, p. 703-709
Wiley-VCH Verlag
Résumé en anglais
The post-functionalization of poly(3-hexylthiophene) (P3HT) via various synthetic routes is reported. Well-defined and monofunctionalized ?-thiol-terminated P3HT, ?-carboxylic acid-terminated P3HT, ?-acrylate-terminated ...Lire la suite >
The post-functionalization of poly(3-hexylthiophene) (P3HT) via various synthetic routes is reported. Well-defined and monofunctionalized ?-thiol-terminated P3HT, ?-carboxylic acid-terminated P3HT, ?-acrylate-terminated P3HT, and ?-methacrylate-terminated P3HT are obtained in high yields through a straightforward procedure. From those, different novel P3HT-based graft copolymers are synthesized following two routes: grafting onto and grafting through (macromonomer polymerization) methods. The synthesis of three types of graft copolymers is described. Each one has rod P3HT-grafted side chains on a coil main chain, which can be polyisoprene, poly(vinyl alcohol), or poly(butyl acrylate). Each copolymer is characterized by size-exclusion chromatography and NMR.< Réduire
Mots clés en anglais
poly(3-hexylthiophene)
graft copolymer
semiconducting copolymer
grafting onto
grafting through
NMRP
thiol-ene reaction
Origine
Importé de halUnités de recherche