α-Halogenoacetanilides as hydrogen-bonding organocatalysts that activate carbonyl bonds: fluorine versus chlorine and bromine
Langue
en
Article de revue
Ce document a été publié dans
Chemistry - A European Journal. 2014, vol. 20, n° 10, p. 2849-2859
Wiley-VCH Verlag
Résumé en anglais
α-Halogenoacetanilides (X=F, Cl, Br) were examined as H-bonding organocatalysts designed for the double activation of CO bonds through NH and CH donor groups. Depending on the halide substituents, the double H-bond involved ...Lire la suite >
Mots clés en anglais
Hydrocarbons
Bromine
Acetanilides
hydrogen bond
chemistry
chemical structure
halogenated hydrocarbon
fluoride
acetanilide derivative
ring-opening polymerization
Fluorine
Catalysis
Chlorine
Fluorides
hydrogen bonds
lactide
noncovalent interactions
organocatalysis
Halogenated
Hydrogen Bonding
Models
Molecular
Quantum Theory