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A comparison between water circulation and terrestrially-driven dissolved silica fluxes to the Mediterranean Sea traced using radium isotopes
GARCIA-ORELLANA, Jordi
Universitat Autònoma de Barcelona = Autonomous University of Barcelona = Universidad Autónoma de Barcelona [UAB]
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Universitat Autònoma de Barcelona = Autonomous University of Barcelona = Universidad Autónoma de Barcelona [UAB]
GARCIA-ORELLANA, Jordi
Universitat Autònoma de Barcelona = Autonomous University of Barcelona = Universidad Autónoma de Barcelona [UAB]
Universitat Autònoma de Barcelona = Autonomous University of Barcelona = Universidad Autónoma de Barcelona [UAB]
STIEGLITZ, Thomas
Centre Européen de Recherche et d'Enseignement des Géosciences de l'Environnement [CEREGE]
Centre for Tropical Water Research & Aquatic Ecosystem Research (TropWATER)
Centre Européen de Recherche et d'Enseignement des Géosciences de l'Environnement [CEREGE]
Centre for Tropical Water Research & Aquatic Ecosystem Research (TropWATER)
RODELLAS, Valenti
Centre Européen de Recherche et d'Enseignement des Géosciences de l'Environnement [CEREGE]
Centre Européen de Recherche et d'Enseignement des Géosciences de l'Environnement [CEREGE]
CLAUDE, Christelle
Centre Européen de Recherche et d'Enseignement des Géosciences de l'Environnement [CEREGE]
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Centre Européen de Recherche et d'Enseignement des Géosciences de l'Environnement [CEREGE]
Langue
EN
Article de revue
Ce document a été publié dans
Geochimica et Cosmochimica Acta. 2018, vol. 238, p. 496-515
Résumé en anglais
The circulation of seawater through permeable coastal sediments is increasingly recognized as an important source of nutrients, including dissolved silica (DSi), to the coastal ocean. Here, we utilized a Ra isotope (223 ...Lire la suite >
The circulation of seawater through permeable coastal sediments is increasingly recognized as an important source of nutrients, including dissolved silica (DSi), to the coastal ocean. Here, we utilized a Ra isotope (223 Ra, 224 Ra ex , 228 Ra) mass balance to quantify DSi fluxes driven by water circulation to a small shallow coastal lagoon (La Palme; French Mediter-ranean) during June 2016, as compared to karstic groundwater spring inputs. The DSi flux driven by lagoon water circulation (derived from 224 Ra ex) was approximately one order of magnitude greater (1900 ± 1700 mol d À1) than the DSi load of the karstic groundwater spring (250 ± 50 mol d À1) and greater than molecular diffusion (970 ± 750 mol d À1). Lagoon water circulation was a negligible source of 228 Ra, indicating that circulation-driven DSi inputs occur over a timescale of days. Offshore transects were studied to quantify fluxes of marine-derived submarine groundwater discharge (SGD) from the permeable sandy coastline adjacent to the lagoon, into the Mediterranean Sea. Surface water transects revealed near-shore enrichments of Ra and DSi, attributed to wave-setup and water exchange through the permeable beach between the lagoon and the sea. Upscaling over the 9.5 km stretch of sandy beaches results in a marine SGD-driven DSi flux of 2.3 ± 1.3 Â 10 4 mol d À1 , similar in magnitude to the Têt river during November 2016 (3.3 ± 2.4 Â 10 4 mol d À1), the largest river in the region. A positive relationship between DSi and 224 Ra ex in lagoon water and seawater, but not 228 Ra, suggests that 224 Ra ex and DSi enrichments are derived from a similar source, the sediment (i.e. lithogenic particle dissolution), operating on short timescales. A marine SGD-driven DSi flux to the Gulf of Lions (3.8 ± 2.2 Â 10 5 mol d À1) is likely continuous over time. The relatively constant DSi inputs from water circulation for the shallow lagoons and beaches along the French Mediterranean Sea< Réduire
Mots clés en anglais
Pore water exchange
Radium isotopes
Submarine groundwater discharge
Mediterranean Sea
Dissolved silica
Circulation
Project ANR
INITIATIVE D'EXCELLENCE AIX MARSEILLE UNIVERSITE - ANR-11-IDEX-0001