Visible-light photocatalyzed oxidative decarboxylation of oxamic acids: a green route to urethanes and ureas
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en
Article de revue
Ce document a été publié dans
Chemical Communications. 2018, vol. 54, n° 67, p. 9337 - 9340
Royal Society of Chemistry
Résumé en anglais
A sustainable metal-free route to urethanes and ureas based on a photocatalyzed oxidative decarboxylation of oxamic acids is described. The reaction includes in situ generation of an isocyanate from the oxamic acid, using ...Lire la suite >
A sustainable metal-free route to urethanes and ureas based on a photocatalyzed oxidative decarboxylation of oxamic acids is described. The reaction includes in situ generation of an isocyanate from the oxamic acid, using an organic dye as a photocatalyst, a hypervalent iodine reagent as an oxidant and a light source, which trigger the free-radical decarboxylation. This protocol successfully avoids the isolation, purification and storage of carcinogenic isocyanates and allows elaboration of urethanes and ureas in a one-pot process from commercially available sources.< Réduire
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