Bio-Based Thermo-Reversible Aliphatic Polycarbonate Network
GRAU, Etienne
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
CRAMAIL, Henri
Laboratoire de Chimie des polymères organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des polymères organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
GRAU, Etienne
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
CRAMAIL, Henri
Laboratoire de Chimie des polymères organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
< Réduire
Laboratoire de Chimie des polymères organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Langue
en
Article de revue
Ce document a été publié dans
Molecules. 2020, vol. 25, n° 1, p. 74
MDPI
Résumé en anglais
Aliphatic polycarbonates represent an important class of materials with notable applications in the biomedical field. In this work, low Tg furan-functionalized bio-based aliphatic polycarbonates were cross-linked thanks ...Lire la suite >
Aliphatic polycarbonates represent an important class of materials with notable applications in the biomedical field. In this work, low Tg furan-functionalized bio-based aliphatic polycarbonates were cross-linked thanks to the Diels-Alder (DA) reaction with a bis-maleimide as the cross-linking agent. The thermo-reversible DA reaction allowed for the preparation of reversible cross-linked polycarbonate materials with tuneable properties as a function of the pendent furan content that was grafted on the polycarbonate backbone. The possibility to decrosslink the network around 70 °C could be an advantage for biomedical applications, despite the rather poor thermal stability of the furan-functionalized cross-linked polycarbonates.< Réduire
Mots clés en anglais
polycarbonates
furan-maleimide
Diels-Alder
bio-based
fatty acids
Origine
Importé de halUnités de recherche