GARBAY, Guillaume; TAILLIEZ, Tiphaine; PAVLOPOULOU, Eleni; ORIOU, Jules; BEZIRDJOGLOU, Mickael; HADZIIOANNOU, Georges; CLOUTET, Eric; BROCHON, Cyril

doi:10.1039/C7PY02056B

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GARBAY, Guillaume
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies

TAILLIEZ, Tiphaine
Laboratoire de Chimie des Polymères Organiques [LCPO]

PAVLOPOULOU, Eleni
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies

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Polymer Chemistry. 2018, vol. 11, p. 1288-1292

Royal Society of Chemistry - RSC

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A series of N1,N4-didodecyl-N1,N4-diphenylbenzene-1,4-diamine based polysquaraines have been synthesized under micro-wave irradiation in the absence of any catalyst. The effect of solvent of polymerization, on the squaric acid catenation (1,2 and 1,3 linkages), has been studied and polysquaraines integrating linear chain in their backbone have been advantageously obtained by using di-functional alcohol during the polymerization. Such obtained polymers exhibit a broad emission with a quantum yield up to 18%. The latter were then tested into OLED devices exhibiting a promising white emission.< Réduire

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polysquaraine

optoelectronic

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Triaryl-1,4-diamine based polysquaraines: effect of co-solvent and monomer insertion on optoelectronic properties

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