Hexaarm star-shaped polystyrenes by core-first method
Langue
en
Article de revue
Ce document a été publié dans
Journal of the Chemical Society, Chemical Communications. 1994 n° 21, p. 2433
Royal Society of Chemistry
Résumé en anglais
The hexafunctional initiator C6[(CH2)2p-C6H4CH(Cl)Me]6 is synthesized by Fe(η-C5H5)+ induced hexabenzylation of C6Me6 followed by regiospecific acetylation, NaBH4 reduction and chlorination, and allows the living cationic ...Lire la suite >
The hexafunctional initiator C6[(CH2)2p-C6H4CH(Cl)Me]6 is synthesized by Fe(η-C5H5)+ induced hexabenzylation of C6Me6 followed by regiospecific acetylation, NaBH4 reduction and chlorination, and allows the living cationic polymerization of styrene which yields hexaarm star-shaped polymers.< Réduire
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