Convenient Synthesis of Hybrid Polymer Materials by AGET-ATRP Polymerization of Pickering Emulsions Stabilized by Cellulose Nanocrystals Grafted with Reactive Moieties
WERNER, Arthur
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
SÈBE, Gilles
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
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Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
WERNER, Arthur
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
SÈBE, Gilles
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
HÉROGUEZ, Valérie
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
< Réduire
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Langue
en
Article de revue
Ce document a été publié dans
Biomacromolecules. 2019, vol. 20, n° 1, p. 490-501
American Chemical Society
Résumé en anglais
We report a novel method to prepare capsules, beads, or open-cell materials from Pickering emulsions of monomers, stabilized by cellulose nanocrystals (CNCs) grafted with reactive isobutyrate bromide moieties (CNC-Br). ...Lire la suite >
We report a novel method to prepare capsules, beads, or open-cell materials from Pickering emulsions of monomers, stabilized by cellulose nanocrystals (CNCs) grafted with reactive isobutyrate bromide moieties (CNC-Br). CNC-Br particles with different hydrophilic/hydrophobic balance at their surface were prepared and subsequently used to stabilize direct (O/W), inverted (W/O), or double emulsions of styrene or n-BuA. The different emulsions obtained were subsequently polymerized, by initiating an AGET-ATRP polymerization from the brominated particles surrounding the stabilized droplets. The different hybrid polymer materials obtained were subsequently characterized, and the impact of the CNCs functionalization and polymerization conditions was particularly discussed.< Réduire
Mots clés en anglais
Cellulose nanocrystals
CNC
Pickering Emulsion
Polymerization
AGET ATRP
direct
inverted
double
Origine
Importé de halUnités de recherche