CHEMTOB, Abraham; VU NGOC, Bao Tram; PINAUD, Julien; LACROIX-DESMAZES, Patrick; HÉROGUEZ, Valérie

doi:10.26434/chemrxiv.9930014.v1

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CHEMTOB, Abraham
Institut de Science des Matériaux de Mulhouse [IS2M]

VU NGOC, Bao Tram
Institut de Science des Matériaux de Mulhouse [IS2M]

PINAUD, Julien
Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]

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While N-heterocyclic carbenes (NHCs) have proven highly effective in various polymerization reactions, the drawback is their high sensitivity towards air and water, which necessitates handling under rigorously anhydrous conditions. In this report, an air-stable two-component NHC photogenerator ─ 2-isopropylthioxanthone (ITX) as photosensitive species and 1,3-bis(mesityl)imidazolium tetraphenylborate (IMesH + BPh4-) acting as NHC protected precursor ─ has been utilized to organocatalyze thiol-Michael reaction for small molecule and polymer synthesis. The feasibility of photoNHC catalysis in addition reactions involving thiol and ene molecules was investigated using 1 H NMR spectroscopy. The synthesis of cross-linked polythioether polymer via a step-growth polymerization was then studied using FTIR spectroscopy, optical pyrometry and gel content measurements.< Leer menos

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Photochemically Activated Thiol-Michael Reactions via a Photolatent N-Heterocyclic Carbene

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