Photodegradation of Myrigalone A, an Allelochemical from Myrica gale : Photoproducts and Effect of Terpenes
GOUPIL, Pascale
Laboratoire de Physique et Physiologie Intégratives de l’Arbre en environnement Fluctuant [PIAF]
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Laboratoire de Physique et Physiologie Intégratives de l’Arbre en environnement Fluctuant [PIAF]
Langue
EN
Article de revue
Ce document a été publié dans
Journal of Agricultural and Food Chemistry. 2019-06-11, vol. 67, n° 26, p. 7258-7265
Résumé en anglais
This study investigated the environmental fate of myrigalone A, a light absorbing natural herbicide found on leaves and fruits of Myrica gale. Myrigalone A was irradiated in water and as a dry solid deposit to simulate ...Lire la suite >
This study investigated the environmental fate of myrigalone A, a light absorbing natural herbicide found on leaves and fruits of Myrica gale. Myrigalone A was irradiated in water and as a dry solid deposit to simulate reactions on leaves, alone and in the presence of the terpenes generated by Myrica gale. The phototransformation was fast (t1/2 = 35 min in water). Analyses by liquid chromatography coupled to high resolution orbitrap electrospray mass spectrometry (MS) and gas chromatography-MS revealed the formation of 11 photoproducts in water and solid and 9 in gaseous phase. Some were detected in the leaf glands and oil covering the fruits of Myrica gale, which suggested that photodegradation occurred in the field. Moreover, myrigalone A photoinduced the oxidation of terpenes that in turn protected it against photolysis. This highlights the need for additional research on the effect of terpenes on the photodegradation of pesticides on vegetation.< Réduire
Mots clés en anglais
H-donor additives
biopesticide
fate
photolysis
medium