Synthesis and Crystallographic Characterization of Helical Hairpin Oligourea Foldamers
| dc.rights.license | open | en_US |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | PENDEM, Nagendar | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | NELLI, Yella‐Reddy | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | CUSSOL, Léonie | |
| dc.contributor.author | DIDIERJEAN, Claude | |
| dc.contributor.author | KAUFFMANN, Brice | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | DOLAIN, Christel | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | GUICHARD, Gilles
IDREF: 084339268 | |
| dc.date.accessioned | 2024-02-12T10:25:44Z | |
| dc.date.available | 2024-02-12T10:25:44Z | |
| dc.date.issued | 2023-05-02 | |
| dc.identifier.issn | 0947-6539 | en_US |
| dc.identifier.uri | oai:crossref.org:10.1002/chem.202300087 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/188037 | |
| dc.description.abstractEn | AbstractOligomers designed to form a helix‐turn‐helix super‐secondary structure have been prepared by covalently bridging aliphatic oligourea foldamer helices with either rigid aromatic or more flexible aliphatic spacers. The relative helix orientation in these dimers was investigated at high resolution using X‐ray diffraction analysis. In several cases, racemic crystallography was used to facilitate crystallization and structure determination. All structures were solved by direct methods. Well‐defined parallel helical hairpin motifs were observed in all cases when 4,4′‐methylene diphenyl diisocyanate was employed as a dimerizing agent, irrespective of primary sequence and chain length. | |
| dc.language.iso | EN | en_US |
| dc.source | crossref | |
| dc.subject.en | Foldamers | |
| dc.subject.en | Helices | |
| dc.subject.en | Racemic crystallography | |
| dc.subject.en | Tertiary structures | |
| dc.subject.en | X-ray diffraction | |
| dc.title.en | Synthesis and Crystallographic Characterization of Helical Hairpin Oligourea Foldamers | |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.1002/chem.202300087 | en_US |
| dc.subject.hal | Chimie/Matériaux | en_US |
| bordeaux.journal | Chemistry - A European Journal | en_US |
| bordeaux.volume | 29 | en_US |
| bordeaux.hal.laboratories | CBMN : Chimie & de Biologie des Membranes & des Nano-objets - UMR 5248 | en_US |
| bordeaux.issue | 39 | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.institution | Bordeaux INP | en_US |
| bordeaux.institution | CNRS | en_US |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| bordeaux.import.source | dissemin | |
| hal.popular | non | en_US |
| hal.audience | Internationale | en_US |
| hal.export | false | |
| workflow.import.source | dissemin | |
| dc.rights.cc | Pas de Licence CC | en_US |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemistry%20-%20A%20European%20Journal&rft.date=2023-05-02&rft.volume=29&rft.issue=39&rft.eissn=0947-6539&rft.issn=0947-6539&rft.au=PENDEM,%20Nagendar&NELLI,%20Yella%E2%80%90Reddy&CUSSOL,%20L%C3%A9onie&DIDIERJEAN,%20Claude&KAUFFMANN,%20Brice&rft.genre=article |
