A new highly sensitive cryogenic luminescent MOF thermometer built with pyromellitic acid
Idioma
en
Article de revue
Este ítem está publicado en
Journal of Materials Chemistry C. 2023, vol. 11, n° 32, p. 10951-10956
Royal Society of Chemistry
Resumen en inglés
A ratiometric thermometer based on a mixed Eu-Tb metal-organic framework is reported with a maximum relative thermal sensitivity of 16.1% K-1 at 11 K making this material one of the best-performing thermometers currently ...Leer más >
A ratiometric thermometer based on a mixed Eu-Tb metal-organic framework is reported with a maximum relative thermal sensitivity of 16.1% K-1 at 11 K making this material one of the best-performing thermometers currently reported in the literature. The sensing mechanism of {[Tb2-xEux(H(2)Btec)(Btec)(H2O)(2)]& BULL;4H(2)O}(n) (Btec = 1,2,4,5 Benzenetetracarboxylic acid) has been attributed to a phonon-assisted energy migration between neighboring Tb3+ ions in the structure.< Leer menos
Proyecto ANR
MOFs à base de lanthanides pour une application de nanothermomètres luminescents - ANR-18-CE09-0008
Orígen
Importado de HalCentros de investigación