MATTEI, Carlo Andrea; MONTIGAUD, Vincent; LEFEUVRE, Bertrand; DORCET, Vincent; ARGOUARCH, Gilles; CADOR, Olivier; LE GUENNIC, Boris; MAURY, Olivier; LALLI, Claudia; GUYOT, Yannick; GUY, Stéphan; GINDRE, Cyprien; BENSALAH-LEDOUX, Amina; RIOBÉ, François; BAGUENARD, Bruno; POINTILLART, Fabrice

doi:10.1039/d3tc00858d

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http://creativecommons.org/licenses/by-nc/

MATTEI, Carlo Andrea
Institut des Sciences Chimiques de Rennes [ISCR]

MONTIGAUD, Vincent
Institut des Sciences Chimiques de Rennes [ISCR]

LEFEUVRE, Bertrand
Institut des Sciences Chimiques de Rennes [ISCR]

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Article de revue

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Journal of Materials Chemistry C. 2023, vol. 11, n° 22, p. 7299-7310

Royal Society of Chemistry

Resumen en inglés

Lanthanide ions have attracted great interest owing to their optical and magnetic properties. Single-molecule magnet (SMM) behavior has been a fascinating science for thirty years. Moreover, chiral lanthanide complexes allow the observation of remarkable circularly polarized luminescence (CPL). However, the combination of both SMM and CPL behaviors in a single molecular system is very rare and deserves attention in the design of multifunctional materials. Four chiral one-dimensional coordination compounds involving 1,1′-Bi-2-naphtol (BINOL)-derived bisphosphate ligands and the Yb(III) centre were synthesized and characterized by powder and single-crystal X-ray diffraction. All the Yb(III)-based polymers displayed field-induced SMM behavior with magnetic relaxation occurring by applying Raman processes and near infrared CPL in the solid state.< Leer menos

DOI

http://dx.doi.org/10.1039/d3tc00858d

Proyecto europeo

MULtiple PROperties Single Molecule Magnets

Proyecto ANR

Luminescence polarisée circulairement de molécules-aimants à base de lanthanide

Orígen

Importado de Hal

Centros de investigación

Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB) - UMR 5026