Towards synergy between spin-crossover and metal-ligands bond break in molecular crystals: structural investigations of eight seven-cordinated Fe(II) macrocyclic complexes
WANG, Hongfeng
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Department of Materials Science and Engineering [Knoxville]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Department of Materials Science and Engineering [Knoxville]
SINITO, Chiara
Laboratoire Photonique, Numérique et Nanosciences [LP2N]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
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Laboratoire Photonique, Numérique et Nanosciences [LP2N]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
WANG, Hongfeng
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Department of Materials Science and Engineering [Knoxville]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Department of Materials Science and Engineering [Knoxville]
SINITO, Chiara
Laboratoire Photonique, Numérique et Nanosciences [LP2N]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire Photonique, Numérique et Nanosciences [LP2N]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
BALDÉ, Chérif
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Chimie et Physique des Matériaux
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Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Chimie et Physique des Matériaux
Langue
en
Article de revue
Ce document a été publié dans
CrystEngComm. 2015, vol. 17, n° 22, p. 4075-4079
Royal Society of Chemistry
Résumé en anglais
Sixteen structures of eight analogical Fe(II) macrocyclic complexes have been investigated exhibiting distinguishable structural properties even though no spin-crossover is observed. Notwithstanding, due to a synergistic ...Lire la suite >
Sixteen structures of eight analogical Fe(II) macrocyclic complexes have been investigated exhibiting distinguishable structural properties even though no spin-crossover is observed. Notwithstanding, due to a synergistic effect between ligand field strength and intermolecular interaction, two of these complexes present very rare evidence for metal–ligand bond break at low temperature.< Réduire
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