DENISOV, Sergey A.; YU, Shinlin; POZZO, Jean-Luc; JONUSAUSKAS, Gediminas; MCCLENAGHAN, Nathan D.

doi:10.1002/cphc.201600137

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Licencia de uso del documento

http://creativecommons.org/licenses/by-nc/

DENISOV, Sergey A.
Institut des Sciences Moléculaires [ISM]
Laboratoire Ondes et Matière d'Aquitaine [LOMA]

YU, Shinlin
Institut des Sciences Moléculaires [ISM]

POZZO, Jean-Luc
Institut des Sciences Moléculaires [ISM]

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Article de revue

Este ítem está publicado en

ChemPhysChem. 2016, vol. 17, n° 12, p. 1794-1804

Wiley-VCH Verlag

Resumen en inglés

Reversible electronic energy transfer (REET) may be instilled in bi-/multichromophoric molecule-based systems, following photoexcitation, upon judicious structural integration of matched chromophores. This leads to a new set of photophysical properties for the ensemble, which can be fully characterized by steady-state and time-resolved spectroscopic methods. Herein, we take a comprehensive look at progress in the development of this type of supermolecule in the last five years, which has seen systems evolve from covalently tethered dyads to synthetic molecular machines, exemplified by two different pseudorotaxanes. Indeed, REET holds promise in the control of movement in molecular machines, their assembly/disassembly, as well as in charge separation.< Leer menos

Palabras clave en inglés

Foldaxanes

Molecular machines

Reversible electronic energy transfer

Time-resolved spectroscopy

Transition metal complexes

DOI

http://dx.doi.org/10.1002/cphc.201600137

Proyecto ANR

Architectures à base de foldamères pour le transport d'electrons - ANR-12-BS08-0007

Orígen

Importado de Hal

Centros de investigación

Laboratoire Ondes et Matière d'Aquitaine (LOMA) - UMR 5798