Viscoelastic properties of confined molecular layers
Idioma
en
Article de revue
Este ítem está publicado en
Journal of Physics: Condensed Matter. 2011-11-09, vol. 23, n° 50, p. 505103
IOP Publishing
Resumen en inglés
We study the viscoelastic properties of a film of n layers of spherical molecules confined between two walls. We find that the dynamic response arises from two competing contributions: the effective stiffness of n C 1 ...Leer más >
We study the viscoelastic properties of a film of n layers of spherical molecules confined between two walls. We find that the dynamic response arises from two competing contributions: the effective stiffness of n C 1 springs in series and softening due to strain fluctuations. In particular, the latter are the origin of the oscillatory behavior of the stiffness and the damping coefficient. The dissipation is strongest at the minima of the stiffness; the inverse behavior may occur for a modulated relaxation time. As a corollary we show that confined molecular layers cannot be described as Maxwell fluids.< Leer menos
Orígen
Importado de HalCentros de investigación