Unusual spin transtion behavior in 2,6-bis(pyrazol-3-yl)-pyridine) iron(II)-bis-oxalato-platinate(II)
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en
Article de revue
Este ítem está publicado en
Journal of Physical Chemistry B. 2007, vol. 111, n° 24, p. 6738-6747
American Chemical Society
Resumen en inglés
[Fe(bpp)2][Pt(ox)2]·H2O (with bpp = 2,6-bis(pyrazol-3-yl)-pyridine and ox = oxalate) was prepared, and its spin crossover behavior was characterized. The two-step spin transition behavior changes over several cycles. The ...Leer más >
[Fe(bpp)2][Pt(ox)2]·H2O (with bpp = 2,6-bis(pyrazol-3-yl)-pyridine and ox = oxalate) was prepared, and its spin crossover behavior was characterized. The two-step spin transition behavior changes over several cycles. The original behavior is restored when the sample is allowed to relax for a week. Furthermore, the ST exhibits a strong dependence on the heating and cooling rate...< Leer menos
Palabras clave en inglés
LIESST
2 6-bis(pyrazol-3-yl)-pyridine) iron(II)-bis-oxalato-platinate(II)
Two step spin transition
Iron(II)
Orígen
Importado de HalCentros de investigación