Crystal structure and magnetic properties of [{Co(H2O)2}2Mo(CN)8]·4 H2O, a three-dimensional cyanide-bridged bimetallic compound
TUNA, Floriana
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Institute of Physical Chemistry
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Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Institute of Physical Chemistry
TUNA, Floriana
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Institute of Physical Chemistry
< Réduire
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Institute of Physical Chemistry
Langue
en
Article de revue
Ce document a été publié dans
Comptes Rendus. Chimie. 2003, vol. 6, n° 3, p. 377-383
Académie des sciences (Paris)
Résumé en anglais
he three-dimensional cyano-bridged bimetallic compound of formula [{Co(H2O)2}2Mo(CN)8]·4 H2O is described. The single-crystal X-ray structural determination revealed that the compound has a polymeric structure based on a ...Lire la suite >
he three-dimensional cyano-bridged bimetallic compound of formula [{Co(H2O)2}2Mo(CN)8]·4 H2O is described. The single-crystal X-ray structural determination revealed that the compound has a polymeric structure based on a network of [MoIV(CN)8] units and CoII ions. Each Mo(CN)8 building block is linked to Co ions through its eight CN ligands and each CoII centre is connected to four Mo units forming a highly symmetrical three-dimensional framework with square-shaped channels running through the structure. The magnetic behaviour in the temperature range 2–300 K and spectroscopic data are reported as well...< Réduire
Mots clés en anglais
Cyanometalate
Molybdenum complex
Cobalt complex
Magnetic properties
Crystal structure
Supramolecular material
Porous framework
Origine
Importé de halUnités de recherche