Crystal structure and magnetic properties of [{Co(H2O)2}2Mo(CN)8]·4 H2O, a three-dimensional cyanide-bridged bimetallic compound
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| hal.structure.identifier | Institute of Physical Chemistry | |
| dc.contributor.author | TUNA, Floriana | |
| hal.structure.identifier | Laboratoire de Chimie du solide et inorganique moléculaire [LCSIM] | |
| dc.contributor.author | GOLHEN, Stéphane | |
| hal.structure.identifier | Organométalliques: Matériaux et Catalyse | |
| dc.contributor.author | OUAHAB, Lahcène | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | SUTTER, Jean-Pascal | |
| dc.date.issued | 2003 | |
| dc.identifier.issn | 1631-0748 | |
| dc.description.abstractEn | he three-dimensional cyano-bridged bimetallic compound of formula [{Co(H2O)2}2Mo(CN)8]·4 H2O is described. The single-crystal X-ray structural determination revealed that the compound has a polymeric structure based on a network of [MoIV(CN)8] units and CoII ions. Each Mo(CN)8 building block is linked to Co ions through its eight CN ligands and each CoII centre is connected to four Mo units forming a highly symmetrical three-dimensional framework with square-shaped channels running through the structure. The magnetic behaviour in the temperature range 2–300 K and spectroscopic data are reported as well... | |
| dc.language.iso | en | |
| dc.publisher | Académie des sciences (Paris) | |
| dc.subject.en | Cyanometalate | |
| dc.subject.en | Molybdenum complex | |
| dc.subject.en | Cobalt complex | |
| dc.subject.en | Magnetic properties | |
| dc.subject.en | Crystal structure | |
| dc.subject.en | Supramolecular material | |
| dc.subject.en | Porous framework | |
| dc.title.en | Crystal structure and magnetic properties of [{Co(H2O)2}2Mo(CN)8]·4 H2O, a three-dimensional cyanide-bridged bimetallic compound | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/S1631-0748(03)00053-5 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Comptes Rendus. Chimie | |
| bordeaux.page | 377-383 | |
| bordeaux.volume | 6 | |
| bordeaux.issue | 3 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00184548 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00184548v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Comptes%20Rendus.%20Chimie&rft.date=2003&rft.volume=6&rft.issue=3&rft.spage=377-383&rft.epage=377-383&rft.eissn=1631-0748&rft.issn=1631-0748&rft.au=TUNA,%20Floriana&GOLHEN,%20St%C3%A9phane&OUAHAB,%20Lahc%C3%A8ne&SUTTER,%20Jean-Pascal&rft.genre=article |
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