BARBIER, Jérémie; CHARON, Nadège; DUPASSIEUX, Nathalie; LOPPINET-SERANI, Anne; MAHÉ, Laure; PONTHUS, Jérémie; COURTIADE, Marion; DUCROZET, Annie; LE MASLE, Agnès; QUOINEAUD, A.A.; CANSELL, François

doi:10.2516/ogst/2012096

Metadatos

Mostrar el registro completo del ítem

Licencia de uso del documento

BARBIER, Jérémie
IFP Energies nouvelles [IFPEN]

CHARON, Nadège
IFP Energies nouvelles [IFPEN]

DUPASSIEUX, Nathalie
IFP Energies nouvelles [IFPEN]

Idioma

Article de revue

Este ítem está publicado en

Oil & Gas Science and Technology - Revue d'IFP Energies nouvelles. 2013, vol. 68, n° 4, p. 741-752

Institut Français du Pétrole (IFP)

Resumen en inglés

In this study, reaction pathway of a woody biomass under hydrothermal conditions is investigated in order to further understand reactions that occur during the thermochemical liquefaction of a lignocellulosic biomass. A multitechnique analytical approach combining chromatographic and spectroscopic techniques has been developed in order to characterize both chemical structure and molecular weight of the products. From our experiments, we can assume that the holocellulosic and the ligneous fractions of biomass have different reactivity under hydrothermal condition. Although hydrothermal conversion of holocellulose and lignin occur both according to a complex pathway composed of competitive fragmentation and condensation reactions, holocellulose reacts first by total fragmentation to low molecular weight compounds followed by the condensation of the fragment to heavy molecular weight compounds, whereas lignin reacts essentially by partial depolymerisation. Since compounds produced from both the holocellulosic and the ligneous fraction are together in the reaction medium then they condense each other during the conversion of lignocellulosic material.< Leer menos

Palabras clave en inglés

Hydrothermal conversion

Lignocellulosic biomass

Macromolecules

Metadatos

Licencia de uso del documento

Correspondence Between Structure and Reactivity During Hydrothermal Conversion of Lignocellulosic Macromolecules

Idioma

Este ítem está publicado en

Resumen en inglés

Palabras clave en inglés

DOI

Orígen

Centros de investigación