Structure–microstructure–property relationships in lead-free BCTZ piezoceramics processed by conventional sintering and spark plasma sintering
BENABDALLAH, Feres
Laboratoire des Matériaux Ferroélectriques
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
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Laboratoire des Matériaux Ferroélectriques
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
BENABDALLAH, Feres
Laboratoire des Matériaux Ferroélectriques
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
< Leer menos
Laboratoire des Matériaux Ferroélectriques
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Idioma
en
Article de revue
Este ítem está publicado en
Journal of the European Ceramic Society. 2015, vol. 35, n° 15, p. 4153–4161
Elsevier
Resumen en inglés
Lead-free piezoelectric ceramics belonging to the pseudo-binary system (1 − x)BaTi0.8Zr0.2O3-x Ba0.7Ca0.3TiO3(BCTZ, x = 0.32 and 0.5) were prepared using conventional sintering and spark plasma sintering. This comparative ...Leer más >
Lead-free piezoelectric ceramics belonging to the pseudo-binary system (1 − x)BaTi0.8Zr0.2O3-x Ba0.7Ca0.3TiO3(BCTZ, x = 0.32 and 0.5) were prepared using conventional sintering and spark plasma sintering. This comparative study shows how the macroscopic properties of ferroelectric BCTZ perovskites are affected when the grain size is decreased. The crystallographic structure and the microstructural characteristics are thoroughly investigated for ceramic samples obtained by both sintering methods. We clearly demonstrate that the dielectric, piezoelectric, pyroelectric and ferroelectric properties in SPS ceramics are strongly affected by the grain size and the structural defects leading to local strain fields which undermine the polarisation flexibility. This confirms that the critical compositions showing remarkably large piezoelectric coefficients are extremely sensitive to external and internal stresses.< Leer menos
Palabras clave en inglés
Lead-free piezoceramics
Spark plasma sintering
ferroelectricity
piezoelectricity
defects
Orígen
Importado de HalCentros de investigación