Sur les phases de type clathrate du silicium et des éléments apparentés (C, Ge, Sn) : Une approche historique

CROS, Christian; POUCHARD, Michel

doi:10.1016/j.crci.2009.05.004

Metadatos

Mostrar el registro completo del ítem

Licencia de uso del documento

CROS, Christian
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

POUCHARD, Michel
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

Idioma

Article de revue

Este ítem está publicado en

Comptes Rendus. Chimie. 2009, vol. 12, n° 9, p. 1014-1056

Académie des sciences (Paris)

Resumen en inglés

This review article relates the history and the recent development of clathrate-type compounds of silicon and related elements (carbon, germanium, tin). Their cage-like structures are identical to those of the gas and liquid hydrates, as well as the silica-based clathrasils . Long time considered as simple crystallographic curiosities, their interest was drastically increased after the discovery of the fullerene forms of carbon. From that time they have been intensively studied for their interesting properties in so various topics as superconducting materials, wide gap semiconductors, super-hard and thermoelectric materials.< Leer menos

Palabras clave en inglés

Clathrates

Hydrates

Clathrasils

Carbon

Silicon

Germanium

Tin

Metadatos

Licencia de uso del documento