SAINT MARTIN, Sabine; MARRE, Samuel; GUIONNEAU, Philippe; CANSELL, François; RENOUARD, Joel; MARCHETTO, Virginie; AYMONIER, Cyril

doi:10.1002/chem.201001600

Métadonnées

Afficher la notice complète

Licence d’utilisation du document

SAINT MARTIN, Sabine
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

MARRE, Samuel
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

GUIONNEAU, Philippe
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

Langue

Article de revue

Ce document a été publié dans

Chemistry - A European Journal. 2010, vol. 16, n° 45, p. 13473-13478

Wiley-VCH Verlag

Résumé en anglais

HNIW or CL20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane) is a nitramine, which is considered as the highest energetic molecular compound known to date, therefore, attracting increasing interest in propulsion applications. Additionally, CL20 is an interesting system for fundamental studies, exhibiting several polymorphs, which can behave as host lattices for trapping guest molecules. Herein, a new CL20 structure that contains inserted CO(2) molecules is reported. A combination of Fourier transform infra red (FTIR) spectroscopy, scanning electron microscopy (SEM), single-crystal X-ray diffraction, and thermal analyses (thermogravimetric analysis coupled with mass spectrometry and differential scanning calorimetry) was used to characterize this new material.< Réduire

Métadonnées

Licence d’utilisation du document

Host-guest inclusion compound from nitramine crystals exposed to condensed carbon dioxide.

Langue

Ce document a été publié dans

Résumé en anglais

DOI

Origine

Unités de recherche