Host-guest inclusion compound from nitramine crystals exposed to condensed carbon dioxide.
Language
en
Article de revue
This item was published in
Chemistry - A European Journal. 2010, vol. 16, n° 45, p. 13473-13478
Wiley-VCH Verlag
English Abstract
HNIW or CL20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane) is a nitramine, which is considered as the highest energetic molecular compound known to date, therefore, attracting increasing interest in propulsion ...Read more >
HNIW or CL20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane) is a nitramine, which is considered as the highest energetic molecular compound known to date, therefore, attracting increasing interest in propulsion applications. Additionally, CL20 is an interesting system for fundamental studies, exhibiting several polymorphs, which can behave as host lattices for trapping guest molecules. Herein, a new CL20 structure that contains inserted CO(2) molecules is reported. A combination of Fourier transform infra red (FTIR) spectroscopy, scanning electron microscopy (SEM), single-crystal X-ray diffraction, and thermal analyses (thermogravimetric analysis coupled with mass spectrometry and differential scanning calorimetry) was used to characterize this new material.Read less <
Origin
Hal imported