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hal.structure.identifierSFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
dc.contributor.authorGRIFFIN, Michael
hal.structure.identifierSFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
dc.contributor.authorSHAKESPEARE, Stephen
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorSHEPHERD, Helena
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorHARDING, Charles J.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDESPLANCHES, Cédric
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorGOETA, Andrés E.
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorHOWARD, Judith A. K.
hal.structure.identifierInstitut für Anorganische Chemie
dc.contributor.authorPOWELL, Annie K.
hal.structure.identifierInstitut of Inorganic Chemistry
dc.contributor.authorMEREACRE, Valeriu
hal.structure.identifierUnité de Chimie des Matériaux Inorganiques et Organiques [UCL CMAT]
dc.contributor.authorGARCIA, Yann
hal.structure.identifierUnité de Chimie des Matériaux Inorganiques et Organiques [UCL CMAT]
dc.contributor.authorNAIK, Anil D.
hal.structure.identifierSFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
dc.contributor.authorMÜLLER-BUNZ, Helge
hal.structure.identifierSFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
dc.contributor.authorMORGAN, Grace G.
dc.date.issued2011
dc.identifier.issn1433-7851
dc.description.abstractEnA two-step magnetic spin transition with accompanying structural phase transitions is reported for the first time for Fe<sup>III</sup>. The transitions are observed at 187 K and 90 K on cooling with a hysteretic transition recorded upon heating during the first crossover at 106 K. The intermediate phase persists over 97 K and contains an unprecedented [HS-HS-LS] motif with tripling of the unit cell
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enA Symmetry-Breaking Spin-State Transition in Iron(III).
dc.typeArticle de revue
dc.identifier.doi10.1002/anie.201005545
dc.subject.halChimie/Matériaux
bordeaux.journalAngewandte Chemie International Edition
bordeaux.page896-900
bordeaux.volume50
bordeaux.issue4
bordeaux.peerReviewedoui
hal.identifierhal-00559541
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00559541v1
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