A Symmetry-Breaking Spin-State Transition in Iron(III).
GRIFFIN, Michael
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
SHAKESPEARE, Stephen
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
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SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
GRIFFIN, Michael
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
SHAKESPEARE, Stephen
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
MÜLLER-BUNZ, Helge
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
MORGAN, Grace G.
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
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SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology
Langue
en
Article de revue
Ce document a été publié dans
Angewandte Chemie International Edition. 2011, vol. 50, n° 4, p. 896-900
Wiley-VCH Verlag
Résumé en anglais
A two-step magnetic spin transition with accompanying structural phase transitions is reported for the first time for Fe<sup>III</sup>. The transitions are observed at 187 K and 90 K on cooling with a hysteretic transition ...Lire la suite >
A two-step magnetic spin transition with accompanying structural phase transitions is reported for the first time for Fe<sup>III</sup>. The transitions are observed at 187 K and 90 K on cooling with a hysteretic transition recorded upon heating during the first crossover at 106 K. The intermediate phase persists over 97 K and contains an unprecedented [HS-HS-LS] motif with tripling of the unit cell< Réduire
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