GRIFFIN, Michael; SHAKESPEARE, Stephen; SHEPHERD, Helena; HARDING, Charles J.; LÉTARD, Jean-François; DESPLANCHES, Cédric; GOETA, Andrés E.; HOWARD, Judith A. K.; POWELL, Annie K.; MEREACRE, Valeriu; GARCIA, Yann; NAIK, Anil D.; MÜLLER-BUNZ, Helge; MORGAN, Grace G.

doi:10.1002/anie.201005545

Metadatos

Licencia de uso del documento

GRIFFIN, Michael
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology

SHAKESPEARE, Stephen
SFI-Strategic Research Cluster in Solar Energy Conversion, Centre for Synthesis and Chemical Biology

SHEPHERD, Helena
Department of Chemistry

Idioma

Article de revue

Este ítem está publicado en

Angewandte Chemie International Edition. 2011, vol. 50, n° 4, p. 896-900

Wiley-VCH Verlag

Resumen en inglés

A two-step magnetic spin transition with accompanying structural phase transitions is reported for the first time for Fe<sup>III</sup>. The transitions are observed at 187 K and 90 K on cooling with a hysteretic transition recorded upon heating during the first crossover at 106 K. The intermediate phase persists over 97 K and contains an unprecedented [HS-HS-LS] motif with tripling of the unit cell< Leer menos

Metadatos

Licencia de uso del documento

A Symmetry-Breaking Spin-State Transition in Iron(III).

Idioma

Este ítem está publicado en

Resumen en inglés

DOI

Orígen

Centros de investigación