Photomagnetism in cyano-bridged hexanuclear clusters [MnII(bpy)2]4[MIV(CN)8]2.xH2O (M = Mo, x = 14, and M = W, x = 9)
Langue
en
Article de revue
Ce document a été publié dans
Chemistry of Materials. 2005, vol. 17 (2), p. 442-449
American Chemical Society
Résumé en anglais
The magnetic and photomagnetic properties of two cyano-bridged, [Mn(bpy)2]4[Mo(CN)8]2·14H2O (1) and [Mn(bpy)2]4[W(CN)8]2·9H2O (2) (bpy = 2,2'-bipyridyl), hexanuclear clusters (hereafter named MnII4MIV2) have been investigated...
Mots clés en anglais
Photomagnetism
Photoinduced magnetic-properties
Crystal structure
Octacyanotungstate(V) ion
Molecular oxygen
Ground state
Complexes
Photochemistry
Luminescence
Reactivity
Photolysis