Structural origin of the gradual spin transition in a mononuclear iron(II) complex
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en
Article de revue
Este ítem está publicado en
Journal of Physics and Chemistry of Solids. 2012, vol. 73, n° 2, p. 193-197
Elsevier
Resumen en inglés
Variable temperature single crystal X-ray diffraction and SQUID magnetometry experiments have revealed a gradual spin transition in [FeII(L)](ClO4)2 (where L=1,4,7-tris(2-aminophenyl)-1,4,7-triazacyclononane), centred ...Leer más >
Variable temperature single crystal X-ray diffraction and SQUID magnetometry experiments have revealed a gradual spin transition in [FeII(L)](ClO4)2 (where L=1,4,7-tris(2-aminophenyl)-1,4,7-triazacyclononane), centred around room temperature. The gradual nature of the spin transition has been attributed to the lack of significant intermolecular interactions between iron centres and the propensity of the counter ions to accommodate the internal strain in the crystal caused by spin crossover.< Leer menos
Palabras clave en inglés
Organometallic compounds
X-ray diffraction
Magnetic properties
Crystal structure
Orígen
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