SCHMIDT, Whitney; BERTHELOT, Romain; ÉTIENNE, Laetitia; WATTIAUX, Alain; SUBRAMANIAN, Mass A.

doi:10.1016/j.materresbull.2013.10.049

Métadonnées

Afficher la notice complète

Licence d’utilisation du document

SCHMIDT, Whitney
Department of Chemistry

BERTHELOT, Romain
Department of Chemistry

ÉTIENNE, Laetitia
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

Langue

Article de revue

Ce document a été publié dans

Materials Research Bulletin. 2014, vol. 50, p. 292-296

Elsevier

Résumé en anglais

A new compound Na3LiFeSbO6 has been synthesized by conventional solid state methods and investigated using X-ray diffraction, DC magnetic susceptibility, 57Fe Mössbauer spectroscopy and optical measurements. This compound crystallizes in a monoclinic unit cell and is related to a family of honeycomb ordered layered oxide materials where Na+ fills octahedral interlayer sites between Li1/3Fe1/3Sb1/3O2 slabs of edge sharing octahedra. Each SbO6 octahedron is surrounded by LiO6 and FeO6 octahedra creating a honeycomb arrangement within the slabs. Powder X-ray diffraction indicates the presence of stacking faults. This compound exhibits Curie-Weiss behavior at high temperatures and the effective magnetic moment verifies the presence of high spin Fe3+. The 57Fe Mössbauer spectroscopy confirms Fe3+ in an octahedral position and indicates disorder in the arrangement of LiO6 and FeO6 octahedra in the Li1/3Fe1/3Sb1/3O2 slabs.< Réduire

Mots clés en anglais

Layered compounds

Magnetic properties

Optical properties

Mössbauer spectroscopy

X-ray diffraction

Métadonnées

Licence d’utilisation du document

Synthesis and characterization of O3-Na3LiFeSbO6: A new honeycomb ordered layered oxide

Langue

Ce document a été publié dans

Résumé en anglais

Mots clés en anglais

DOI

Origine

Unités de recherche