Interplay between a Foldamer Helix and a Macrocycle in a Foldarotaxane Architecture
| dc.rights.license | open | en_US |
| dc.relation.isnodouble | 54f40d82-c1ee-4a51-a7dc-a3873ce4928d | * |
| dc.relation.isnodouble | d3e9affd-c524-4b95-a31c-566d7ca6ec51 | * |
| dc.contributor.author | GAUTHIER, Maxime | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | KOEHLER, Victor | |
| dc.contributor.author | CLAVEL, Caroline | |
| hal.structure.identifier | Institut Européen de Chimie et Biologie [IECB] | |
| dc.contributor.author | KAUFFMANN, Brice | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | HUC, Ivan | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | FERRAND, Yann | |
| dc.contributor.author | COUTROT, Frederic | |
| dc.date.accessioned | 2021-07-05T09:32:01Z | |
| dc.date.available | 2021-07-05T09:32:01Z | |
| dc.date.issued | 2021 | |
| dc.identifier.issn | 1433-7851 | en_US |
| dc.identifier.other | https://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202100349&file=anie202100349-sup-0001-misc_information.pdf | en_US |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/94970 | |
| dc.description.abstractEn | The design and synthesis of a novel rotaxane/foldaxane hybrid architecture is reported. The winding of an aromatic oligoamide helix host around a dumbbell-shaped thread-like guest, or axle, already surrounded by a macrocycle was evidenced by NMR spectroscopy and X-ray crystallography. The process proved to depend on the position of the macrocycle along the axle and the associated steric hindrance. The macrocycle thus behaves as a switchable shield that modulates the affinity of the helix for the axle. Reciprocally, the foldamer helix acts as a supramolecular auxiliary that compartmentalizes the axle. In some cases, the macrocycle is forced to move along the axle to allow the foldamer to reach its best recognition site. | |
| dc.description.sponsorship | Des FoldaRotaxanes pour la Synthèse généralisée de Molécules Entrelacées Improbables - ANR-17-CE07-0014 | en_US |
| dc.language.iso | EN | en_US |
| dc.subject.en | crystallography | |
| dc.subject.en | foldamers | |
| dc.subject.en | molecular motion | |
| dc.subject.en | rotaxanes | |
| dc.title.en | Interplay between a Foldamer Helix and a Macrocycle in a Foldarotaxane Architecture | |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.1002/anie.202100349 | en_US |
| dc.subject.hal | Chimie/Matériaux | en_US |
| bordeaux.journal | Angewandte Chemie-International Edition | en_US |
| bordeaux.page | 8380-8384 | en_US |
| bordeaux.volume | 60 | en_US |
| bordeaux.hal.laboratories | Institut de Chimie & de Biologie des Membranes & des Nano-objets (CBMN) - UMR 5248 | en_US |
| bordeaux.issue | 15 | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.institution | Bordeaux INP | en_US |
| bordeaux.institution | CNRS | en_US |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| hal.identifier | hal-03247517 | |
| hal.export | false | |
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