Cyclobishelicenes: Shape-Persistent Figure-Eight Aromatic Molecules with Promising Chiroptical Properties
dc.rights.license | open | en_US |
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
dc.contributor.author | ROBERT, Antoine | |
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
dc.contributor.author | NAULET, Guillaume | |
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
dc.contributor.author | BOCK, Harald | |
dc.contributor.author | VANTHUYNE, Nicolas | |
dc.contributor.author | JEAN, Marion | |
dc.contributor.author | GIORGI, Michel | |
dc.contributor.author | CARISSAN, Yannick | |
dc.contributor.author | AROULANDA, Christie | |
hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
dc.contributor.author | SCALABRE, Antoine | |
hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
dc.contributor.author | POUGET, Emilie | |
hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
dc.contributor.author | DUROLA, Fabien | |
dc.contributor.author | COQUEREL, Yoann | |
dc.date.accessioned | 2020-05-06T13:39:54Z | |
dc.date.available | 2020-05-06T13:39:54Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 0947-6539 | en_US |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/7492 | |
dc.description.abstractEn | Cyclobis[n]helicenes (n=3 or 5) are chiral D2 -symmetric pi-conjugated macrocycles with stable lemniscular, or figure-eight, shapes. The conformational analysis of five different cyclobis[n]helicenes revealed that these molecules can only exist as their lemniscular conformers with high barriers to enantiomerization (>200 kJmol-1 ). The enantiomers of a cyclobis[5]helicene were resolved by HPLC and their unusual chiroptical properties were attributed to the inherent chirality of their macrocyclic figure-eight. | |
dc.language.iso | EN | en_US |
dc.subject.en | aromatic compounds | |
dc.subject.en | chirality | |
dc.subject.en | chiroptical properties | |
dc.subject.en | conformation analysis | |
dc.subject.en | helical structures | |
dc.title.en | Cyclobishelicenes: Shape-Persistent Figure-Eight Aromatic Molecules with Promising Chiroptical Properties | |
dc.type | Article de revue | en_US |
dc.identifier.doi | 10.1002/chem.201902637 | |
dc.subject.hal | Chimie/Matériaux | en_US |
bordeaux.journal | Chemistry (Weinheim an der Bergstrasse, Germany) | en_US |
bordeaux.page | 14364-14369 | en_US |
bordeaux.volume | 25 | en_US |
bordeaux.hal.laboratories | Institut de Chimie & de Biologie des Membranes & des Nano-objets (CBMN) - UMR 5248 | en_US |
bordeaux.issue | 63 | en_US |
bordeaux.institution | Bordeaux INP | en_US |
bordeaux.institution | Université de Bordeaux | en_US |
bordeaux.peerReviewed | oui | en_US |
bordeaux.inpress | non | en_US |
hal.identifier | hal-03182123 | |
hal.version | 1 | |
hal.date.transferred | 2021-03-26T09:40:32Z | |
hal.export | true | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemistry%20(Weinheim%20an%20der%20Bergstrasse,%20Germany)&rft.date=2019&rft.volume=25&rft.issue=63&rft.spage=14364-14369&rft.epage=14364-14369&rft.eissn=0947-6539&rft.issn=0947-6539&rft.au=ROBERT,%20Antoine&NAULET,%20Guillaume&BOCK,%20Harald&VANTHUYNE,%20Nicolas&JEAN,%20Marion&rft.genre=article |
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