Toward hydrogenase mimicry : subjecting the problem to three different approaches
| dc.contributor.author | DE HATTEN, Xavier | |
| dc.date | 2006-11-14 | |
| dc.date.accessioned | 2021-01-13T14:03:40Z | |
| dc.date.available | 2021-01-13T14:03:40Z | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/25396 | |
| dc.description.abstractEn | In this work, the challenging task of modelling Hydrogenase is subjected to three different approaches. The first strategy used here is bioorganometallic. A wide range of sulfur containing ferrocene-peptide derivatives were synthesized and fully characterized. A new class of structural mimic of Fe-only hydrogenase with ferrocene-peptide backbone was obtained. In the second approach, a theoretical computational study of the ferrocene peptide derivatives is led. In order to investigate a wider range of ferrocene-peptide as a molecular scaffold, a molecular force field was successfully implemented in CHARMM27. As a third approach, organic self-assembled oligoquinoline were studied as potential scaffold of hydrogenase mimics. | |
| dc.format | application/pdf | |
| dc.language | en | |
| dc.rights | free | |
| dc.subject | Sciences chimiques | |
| dc.subject | Hydrogenase | |
| dc.subject | ferrocene peptide | |
| dc.subject | CHARMM27 | |
| dc.subject | organic self-assembled oligoquinoline | |
| dc.title | Toward hydrogenase mimicry : subjecting the problem to three different approaches | |
| dc.type | Thèses de doctorat | |
| bordeaux.hal.laboratories | Thèses Bordeaux 1 Ori-Oai | * |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.title=Toward%20hydrogenase%20mimicry%20:%20subjecting%20the%20problem%20to%20three%20different%20approaches&rft.atitle=Toward%20hydrogenase%20mimicry%20:%20subjecting%20the%20problem%20to%20three%20different%20approaches&rft.au=DE%20HATTEN,%20Xavier&rft.genre=unknown |
